Polypropylene (PP) was discovered at the beginning of the 50’s while various research groups around the world were working on the polymerization of olefins. Several of them managed to synthesize solid PP in the laboratory, although it was not suitable for industrial use.
It was not until 1953 when Karl Ziegler managed to make it high-density thanks to organometallic catalysts that would eventually be called Ziegler catalysts. One year later, Giulio Natta, following the work carried out by Ziegler, managed to obtain isotactic polypropylene, this means with a very regular structure. As a curiosity, it must be stated that all this work was so relevant that both researchers shared a Nobel Prize in Chemistry.
In 1957, PP began to be commercialized in Europe and North America. However, despite being semi-crystalline and affordable, surpassing polyethylene in mechanical properties and having the lowest density, it was highly sensitive to cold and ultraviolet light. This is why it was reduced to few applications, basically domestic utensils.
Later on, with the discovery of new light stabilizers and the greater resistance to cold achieved with propylene, these inconveniences were solved and it began to have increasingly new applications, especially for automotive products. From 1983, due to several mergers between the main producers, the production and commercialization of PP significantly increased until nowadays.